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12. Enantioselective C–H Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated Alkene

Angew. Chem., Int. Ed. 2014, 53, 11890.

Peng Yu, Jin-Shun Lin, Lei Li, Sheng-Cai Zheng, Ya-Ping Xiong, Li-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu,*

Highlighted by “Synfacts 2014, 10, 1281”. Highlighted by “Angew. Chem., Int. Ed. 2017, 56, 49”.

11.Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid

Angew. Chem., Int. Ed. 2014, 53, 3684.

Dao-Juan Cheng, Liang Yan, Shi-Kai Tian,* Ming-Yue Wu, Lu-Xin Wang, Zi-Li Fan, Sheng-Cai Zheng, Xin-Yuan Liu,* and Bin Tan,*

Highlighted by “Synfacts 2014, 10, 530”.

 

10.Amide Groups Switch Selectivity: C–H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation

Org. Lett., 2014, 16, 6032.

Lei Li, Jing-Yao Guo, Xing-Guo Liu, Su Chen, Yong Wang, Bin Tan,* and Xin-Yuan Liu,*

9.Copper-Catalyzed Aminotrifluoromethylation of Unactivated Alkenes with TMSCF₃: Construction of Trifluoromethylated Azaheterocycles

J. Org. Chem. 2014, 79, 7084.

Jin-Shun Lin, Xiang-Geng Liu, Xiao-Long Zhu, Bin Tan,* and Xin-Yuan Liu,*

8.In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles

Org. Lett. 2014, 16, 2192.

Xing-Li Zhu, Jin-Hui Xu, Dao-Juan Cheng, Li-Jiao Zhao, Xin-Yuan Liu,* and Bin Tan,*

Highlighted by “Synfacts 2014, 10, 754”.

7.Direct Access to α-CF₃-enones via Efficient Copper-Catalyzed Trifluoromethylation of Meyer-Schuster Rearrangement

Ya-Ping Xiong, Ming-Yue Wu, Xiang-Yu Zhang, Can-Liang Ma, Lin Huang, Li-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu,*

Org. Lett. 2014, 16, 1000.

This work is highlighted on the website http:// http://www.organic-chemistry.org/abstracts/lit4/389.shtm

6.Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles

Lei Li, Min Deng, Sheng-Cai Zheng, Ya-Ping Xiong, Bin Tan,* and Xin-Yuan Liu,*

Org. Lett. 2014, 16, 504.

5.Efficient Copper-Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen-Based Nucleophiles

Jin-Shun Lin, Ya-Ping Xiong, Can-Liang Ma, Li-Jiao Zhao, Bin Tan,* and Xin-Yuan Liu,*

Chem. Eur. J. 2014, 20, 1332.

4.Straightforward Installation of Carbon-Halogen, Carbon-Oxygen and Carbon-Carbon Bonds within Metal–Organic Frameworks via Direct C–H Functionalization

Chem. Commun. 2014, 50, 13261.

Tao Liu, Da-Qiang Li, Si-Yu Wang Yong-Zhou Hu, Xiao-Wu Dong,* Xin-Yuan Liu,* and Chi-Ming Che,

Highlighted by “Synfacts 2014, 10, 1272”.

3.Alkenyl/thiol-derived Metal–Organic Frameworks via Post-Synthetic Modification for Effective Mercury Adsorption

Tao Liu, Jin-Xin Che, Yong-Zhou Hu, Xiao-Wu Dong,* Xin-Yuan Liu,* and Chi-Ming Che

Chem. Eur. J. 2014, 20,14090.