Publications 2021 – Xin-Yuan Liu Research Group

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87. “Copper-Catalyzed Intermolecular Enantioselective Radical Oxidative C(sp3)−H/C(sp)−H Cross-Coupling with Rationally Designed Oxazoline-Derived N,N,P(O)-Ligand”

Angew. Chem. Int. Ed. 2021, 60, 26710. SI

Lin Liu, Kai-Xin Guo, Yu Tian, Chang-Jiang Yang, Qiang-Shuai Gu, Zhong-Liang Li, Liu Ye*, and Xin–Yuan Liu*

86. “Enantioconvergent Cu-Catalyzed Radical C−N Coupling of Racemic Secondary Alkyl Halides to Access α‑Chiral Primary Amines”

J. Am. Chem. Soc. 2021, 143, 15413. SI

Yu-Feng Zhang+, Xiao-Yang Dong+, Jiang-Tao Cheng+, Ning-Yuan Yang, Li-Lei Wang, Fu-Li Wang, Cheng Luan, Juan Liu, Zhong-Liang Li, Qiang-Shuai Gu, and Xin-Yuan Liu*

Spotlights on Recent JACS Publications.

Highlighted by Synfacts 2021, 17(12), 1358.

85. “Catalytic enantioselective C(sp3)–Hfunctionalization involving radical intermediates”

Nat. Commun. 2021, 12, 475.

Chi Zhang, Zhong-Liang Li, Qiang-Shuai Gu* & Xin-Yuan Liu*

Invited Perspective

84. “Copper-Catalyzed Asymmetric Coupling of Allenyl Radicals with Terminal Alkynes to Access Tetrasubstituted Allenes”

Angew. Chem. Int. Ed. 2021, 60, 2160. SI

Xiao-Yang Dong+, Tian-Ya Zhan+, Sheng-Peng Jiang, Xiao-Dong Liu, Liu Ye, Zhong-Liang Li, Qiang- Shuai Gu, and Xin-Yuan Liu*

83. “Copper-Catalyzed Enantioconvergent Cross-Coupling of Racemic Alkyl Bromides with Azole C(sp³)–H Bonds”

Angew. Chem. Int. Ed. 2021, 60, 380. SI

Xiao-Long Su+, Liu Ye+, Ji-Jun Chen+, Xiao-Dong Liu+, Sheng-Peng Jiang, Fu-Li Wang, Lin Liu, Chang-Jiang Yang, Xiao-Yong Chang, Zhong-Liang Li, Qiang-Shuai Gu, and Xin-Yuan Liu*

Highlighted by Synfacts 2020,16(12), 1442.

82. “Ligand-Enabled Copper(I)-Catalyzed Asymmetric Radical C(sp3)−C Cross-Coupling Reactions”

ACS Catal. 2021, 11, 7978.

Huan Zhou+, Zhong-Liang Li+, Qiang-Shuai Gu, and Xin-Yuan Liu*

81. “Copper-Catalyzed Radical 1,2-Carbotrifluoromethylselenolation of Alkenes under Ambient Conditions”

Org. Lett. 2021, 23, 1945. SI

Jiao Yu, Ning-Yuan Yang, Jiang-Tao Cheng, Tian-Ya Zhan, Cheng Luan, Liu Ye, Qiang-Shuai Gu, Zhong-Liang Li,* Guo-Qiang Chen,* and Xin-Yuan Liu*

80. “Recent Advances in Radical-Involved Alkynylation of Unactivated C(sp³)–H Bonds by Hydrogen Atom Abstraction”

Synlett, 2021, 32, 362.

Zheng-Hua Zhang, He Wei, Zhong-Liang Li*, Xin-Yuan Liu*

Invited submission for SYNLETT issue in the Cluster Section “Radicals – by Young Chinese Organic Chemists”

Cluster Preface

79. “A general copper-catalyzed radical C(sp³)-C(sp²) cross-coupling to access 1,1-diarylalkanes under ambient conditions”

Tetrahedron, 2021, 89, 132152. SI

Xiao-Long Su+, Sheng-Peng Jiang+, Liu Ye , Guo-Xing Xu, Ji-Jun Chen, Qiang-Shuai Gu, Zhong-Liang Li* , Xin-Yuan Liu*

Special Issue in honor of Guangbin Dong who recently received the 2021 Tetrahedron Young Investigator Award in Organic Synthesis.

78. “A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp3)−C(sp2) Cross-Coupling with Chiral Multidentate N,N,P‑Ligand”

Organometallics, 2021, 40, 2215. SI

Zhuang Li+, Xian-Yan Cheng+, Ning-Yuan Yang, Ji-Jun Chen, Wen-Yue Tang, Jun-Qian Bian, Yong-Feng Cheng, Zhong-Liang Li, Qiang-Shuai Gu,* and Xin-Yuan Liu*

Invited submission for Special Issue Organometallic “Solutions to Challenges in Cross-Coupling”

Photoinduced Copper-Catalyzed Asymmetric C—O Cross-Coupling